The synergistic action of cyclodextrin-based adsorbent and advanced oxidation processes for sulfamethoxazole removal from water
Author/s
Rizzi, V; Romita, R; Gómez López, Vicente Manuel; Gubitosa, J; Gabaldón, José Antonio; [et al.]Date
2022-01-29Discipline/s
Ciencias AmbientalesSubject/s
Adsorbent regenerationAdsorption
Emerging contaminants
Photocatalytic degradation
Polymers
Pulsed light
Abstract
In this work, the removal of sulfamethoxazole from water was studied by adsorption on a cyclodextrin–epichlorohydrin copolymer and through Advanced Oxidation Processes. The adsorption was efficient and fast, requiring only 10 min to reach the equilibrium; it was also highly favored, with adsorption efficiency higher than 80%, at slightly acidic pH and at room temperature. The desorption of sulfamethoxazole was obtained by raising the temperature to 80 °C. The regenerated polymer has been reused multiple times without any loss in performance, allowing a reduction in costs associated with the process. As an alternative method to regenerate the adsorbent material, the photodegradation of sulfamethoxazole adsorbed on the polymer alone and in the presence of TiO2 as a catalyst through continuous irradiation with UV light and Pulsed Light was attempted and studied. For this purpose, polymeric adsorbents containing different amounts of TiO2 were synthesized and tested. The Pulsed Light show...